Conflict changed Assad, says friend "They are artillery shells and rockets that can be moved easily to Hezbollah," he added.
But Sillu denied remarks attributed to him that he had attended a meeting before he defected, during which the possible use of chemical weapons was discussed.
Sillu said he had heard that Syrian and Iranian experts were doing joint research at the long-established chemical weapons facility at Al Safir near Aleppo, where there is a complex of tunnels and a base for Scud missiles.
"There are warehouses there," he said, "used for experiments on poisonous grenades that contain sarin gas, tabun gas and mustard gas."
In a telephone interview from Turkey, Sillu told CNN that much of Syria's arsenal comprised poisonous gases.
"It's the weapon of choice for poor countries and Syria has large quantities of them. They sometimes takes the liquid form, and can be used in artillery shells or rockets," he said.
Of the several videos posted, the most detailed is about a military installation southwest of Damascus in al-Mazzeh, where a large military airport is situated.
An unnamed narrator says: "The chemical warehouse is connected with an underground tunnel that goes to the airport." The narrator identifies what appears to be the tunnel's exit. He says the tunnel is large enough to accommodate trailers.
There is no way for CNN to verify the descriptions given of the images, but the narrator claims considerable knowledge of the area. After zooming in, he points out a building described as housing equipment for ventilating the tunnel.
He says the warehouse is highly fortified with reinforced concrete that would be difficult to penetrate, even with cruise missiles. The area is called "Mezeh-86 and no-one can get in or out of it," he adds.
"The warehouse contains many chemical weapons, chemical bombs of different sizes, from the size of a hand grenade up to big rockets," he adds.
Sillu told CNN there was a chemical battalion headquarters in the area, but disputed there were warehouses of chemical weapons at the base.
The narrator also claims there are "experts from North Korea and Iran" housed in a building close by.
Again, it is impossible to confirm such claims, but Sillu said the head of the Syrian chemical warfare command had visited Iran and North Korea several times "to buy protective equipment against poisonous materials, and chemical equipment."
The possibility that the security of Syria's arsenal of chemical weapons and precursors might be compromised as fighting spreads is a source of deep concern to the Obama administration.
President Barack Obama himself said on August 20: "We have been very clear to the Assad regime -- but also to other players on the ground -- that a red line for us is we start seeing a whole bunch of chemical weapons moving around or being utilized."
"That would change my calculus; that would change my equation," the president said.
A U.S. official told CNN Friday the intelligence community believes it has a strong sense of where the weapons are and feels confident they remain under Syrian government control.
In another of the videos, a narrator identifying himself as Abou Sayyad uses Google Earth to illustrate an area between two settlements close to Damascus -- Al-Tal and Ish Al-Warwar. He describes the area as mountainous with poor roads. Zooming in, he points to an area that appears to show tunnels off a main road.
"This is a network of tunnels deep in the mountains that is secured against chemical and nuclear attacks where chemical and biological weapons are stored," he says.
He says that the tunnels are split into storage facilities -- some of them up to 500 meters (1,640 feet) inside the mountain -- that are in turn separated in case of an accident or explosion.
The narrator of this second video says the storage facility includes "chemical weapons, including [the nerve agent] VX, mustard, chlorine and phosphorus."
CNN has no way of independently confirming what, if anything, is held at this site.
The narrator claims: "I entered this tunnel with an officer and went in a distance of about 100 or 200 meters (328 to 656 feet). There were separate warehouses on the left and right with very thick doors. One of the doors I saw was about 50 centimeters (20 inches) thick and made of steel."
In a third video, it's claimed that Scud rockets equipped with chemical warheads are situated in a remote area off the highway between Damascus and the town of Qutaifa. The four-minute video hovers over satellite imagery from this year -- zooming into an area that appears to show two missiles described as "rockets with their launching platforms."
"We want all Syrian people to see this video, so the message will reach whoever is working in this location," the narrator says.
Another video zooms in on another area northeast of Damascus -- and highlights a barrier said to be made of dirt running alongside the highway. In the eight-minute video, the narrator says that to the north of the highway is a chemical weapons storage facility "where experts from Iran and North Korea are present."
He also claims part of the area had been sprayed with a highly reflective material to prevent satellites from capturing clear images.
The videos were uploaded by the Saned News Network -- an anti-regime activist group.
The Syrian government has repeatedly denied that its chemical weapons are at risk or would be deployed.
But Sillu argues: "If the Free Syrian Army captured a big city like Aleppo for example, this regime will not hesitate in using these weapons."
CNN's Tracy Doueiry contributed to this report.
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